Physic-topological simulation of a high-voltage coaxial ion diode with a wire metal cathode at atmospheric nitrogen pressure in the hydrodynamic drift-diffusion approximation is performed. The reactions of nitrogen ionization by electrons, attachment of electrons to nitrogen molecules with the formation of negative ions, recombination of charged particles with opposite signs of charge, secondary ion-electron emission of the cathode were taken into account. The distribution of potential and density (concentration) of charged particles in the interelectrode gap, the density of ionic and electron currents at the electrodes were calculated within the self-consistent problem with the following parameters: diameter of wire metal cathode 0.01-0.16 mm, diameter of tubular anode 6 or 20 cm, voltage 20-40 kV, gas temperature 300 or 600K. The influence of geometry, voltage and gas temperature on the discharge parameters has been determined. The obtained calculated data on the discharge current are consistent with the experiment. It is shown that two zones are formed in the discharge between the electrode gap – one is with a width of about 1 mm with a strong and rapidly changing electric field near the cathode and the second long zone with the drift of charged particles towards the anode with a smaller but constant field strength. This is a characteristic feature of negative corona discharges. In the cathode zone there is an intensive ionization of nitrogen with the generation of positive ions and electrons. In the second zone, the density of positive ions decreases sharply due to recombination and weak ionization. The reaction of attachment of electrons to nitrogen molecules begins almost near the cathode surface and continues throughout the cathode zone, in the drift zone the concentration of negative ions gradually decreases. Moreover, the role of electronic conductivity is greatly reduced as we approach the anode. Due to the low mobility of negative ions and, accordingly, the high electrical resistance of the drift zone, the voltage drop on this space part represents a significant portion of the discharge voltage (~1.5 kV on the cathode zone and 18.5 kV on the drift space, at the total voltage of 20 kV). The fact that the highest concentration of positive ions is formed near the cathode, and negative – along the entire interelectrode gap, it can be used, respectively, in the processes of ionic nitriding of wire cathode metal materials and for processing materials and biological substances (bacteria, viruses, fungi), sensitive to negative ions, at the location of the carriers of these substances near the anode. To implement the latter, it is advisable to modify the design of the external anode for efficient extraction of nitrogen ions into the environment. It is also advisable to continue research in the direction of increasing the energy efficiency of ion generation by determining the method of the maximum allowable reduction of the voltage drop on the space of drift of charged particles.
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