Оптичні властивості наночастинок нікелю в системах зі статистично неоднорідною структурою

Oleksandr Viktorovich Machulianskyi

doi:10.20535/2523-4455.2018.23.1.126231

Vol. 23 · Issue 1 · 2018 Feb 28, 2018 Solid-state electronics

Optical properties of nickel nanoparticles in systems with a statistically inhomogeneous structure

Oleksandr Viktorovich Machulianskyi Corresponding Національний технічний університет України “Київський політехнічний інститут імені Ігоря Сікорського” Ukraine

Pages6-15 PublishedFeb 28, 2018

PDF (Ukrainian)

VOL 23 · ISS 1 · 2018 View issue

Abstract

The analysis and further development of the experimental-analytical approach for determining the values of the optical parameters of nanosized particles for a system with a statistically inhomogeneous structure is presented. An improved experimental-analytical method for determining the complex specific electric polarizability of nanosized particles in systems with a statistically inhomogeneous structure is based on spectrophotometric and electron-microscopic measurements on two-dimensional structures and application of analytical solution of Rosenberg’s spectrophotometric equations with the consideration of analysis of particle size distribution. Experimental spectrophotometric and electron-microscopic studies of nickel islet films with weight thickness from 0.3 nm to 2.0 nm deposited by high-vacuum sputtering on quartz substrates in the range of the spectrum 0.2 ÷ 1, 1 μm are performed. Islands nickel film presented morphological microstructure in the form of monolayers isolated from each other nanoislands spherical surface nickel concentration (0.8 ÷ 2.0) · 10 12 cm -2 and an average particle diameter 2.5 ÷ 7 nm. The optical characteristics, namely, the complex specific electric polarizability, optical electric conductivity of nanosized nickel particles are determined in the spectral range 0.2 ÷ 1.1 μm with the help of the improved experimental-analytical method. A significant increase to one order of magnitude of the absolute values of complex specific electric polarizability of nickel particles with a decrease in their size and in comparison with absolute values of complex specific electric polarizability of model spheres with refractive index and absorption index of nickel in macroscopic volumes was revealed. It is established that in the spectral dependences of optical electric conductivity of nickel nanoparticles in the range 0.2 ÷ 1.1 μm there is a band that diminishing size is shifted to a high-frequency region. In this case, the value of optical electric conductivity of nickel nanoparticles monotonically decreases with a decrease in the size by 1-2 orders of magnitude. Comparison of the obtained values of optical electric conductivity of particles in the range of the considered interval with the values of optical electric conductivity of macroscopic samples of nickel in the studied range of the spectrum shows that in particles the value of optical electric conductivity is 2-3 orders of magnitude smaller than that of massive metals. It is shown that in the nanoparticles of nickel absorption of “Drude” type in the near infrared region the spectrum is suppressed. The reason for this phenomenon may be the change of the mechanism of low-frequency electromagnetic response in nanosized metal particles in comparison with macroscopic metals. The research results are of interest for the development and optimization of nanostructured systems with the inclusion of nanosized nickel particles and functional devices based on them with given electromagnetic characteristics. Ref. 22, fig. 4.

Keywords

#electric polarizability #nanosized particles #experimental-analytical method

References

Y. I. Petrov, Fizika malyih chastits [Physics of small particles] . Moscow, USSR: Nauka, 1982.
A. Borisova, B. Babych, V. Verbitskiy, A. Machulyansky, M. Rodionov, and Y. Yakimenko, “Energy-efficient optically transparent coating based on a metal-dielectric composites,” in 2015 IEEE 35th International Conference on Electronics and Nanotechnology (ELNANO) , 2015, pp. 93–96, DOI: 10.1109/ELNANO.2015.7146842 .
E. Moulin, J. Sukmanowski, P. Luo, R. Carius, F. X. Royer, and H. Stiebig, “Improved light absorption in thin-film silicon solar cells by integration of silver nanoparticles,” J. Non. Cryst. Solids , vol. 354, no. 19–25, pp. 2488–2491, 2008, DOI: 10.1016/j.jnoncrysol.2007.09.031 .
A. Borisova et al. , “Modeling of metal-dielectric nanocomposite coatings with ferromagnetic inclusions for electromagnetic protection of electronic devices,” in 2014 IEEE 34th International Scientific Conference on Electronics and Nanotechnology (ELNANO) , 2014, pp. 139–141, DOI: 10.1109/ELNANO.2014.6873955 .
I. S. Edel’man et al. , “Microstructure and magnetooptics of silicon oxide with implanted nickel nanoparticles,” J. Exp. Theor. Phys. , vol. 113, no. 6, pp. 1040–1049, 2011, DOI: 10.1134/S1063776111160035 .
A. V. Kalenskii, M. V. Anan’eva, A. A. Zvekov, and I. Y. Zykov, “Spektralnaya zavisimost kriticheskoy plotnosti energii initsiirovaniya kompozitov na osnove pentaeritrittetranitrata s nanochastitsami nikelya [Spectrum dependence of the critical energy density of composites based on pentaerythritol tetranitrate with nikel nanoparticles],” Basic Probl. Mater. Sci. , vol. 11, no. 3, pp. 340–345, 2014, URL: http://www.nsmds.ru/journal/720.html .
A. Borisova, B. B. A. Machulyansky, M. Rodionov, and Y. Yakimenko, “Properties of aluminum oxynitride films prepared by reactive magnetron sputtering,” in 2014 IEEE 34th International Scientific Conference on Electronics and Nanotechnology (ELNANO) , 2014, pp. 188–190, DOI: 10.1109/ELNANO.2014.6873942 .
E. A. Bondar, “Razmernyie zavisimosti opticheskih harakteristik malyih chastits serebra v vyisokochastotnoy oblasti spektra [Size dependences of the optical characteristics of small silver particles in the high-frequency region of the spectrum],” Opt. Spectrosc. , vol. 77, no. 3, pp. 414–420, 1994.
O. V. Machulianskyi, “Razmernyie zavisimosti dinamicheskoy polyarizuemosti ultradispersnyih chastits [Dimensional dependences of the dynamic polarizability of ultradisperse particles],” Electron. Commun. , vol. 6, no. 10, pp. 78–80, 2001.
J. P. Marton and M. Schlesinger, “Optical Constants of Thin Discontinuous Nickel Films,” J. Appl. Phys. , vol. 40, no. 11, pp. 4529–4533, 1969, DOI: 10.1063/1.1657227 .
G. V. Rozenbepg, Optika tonkosloynyih pokryitiy [Optics of thin-layer coatings] . Moscow, USSR, 1958.
E. A. Bondar and A. V. Machulianskyi, “Spektrofotometricheskiy metod opredeleniya dinamicheskoy polyarizuemosti ultradispersnyih metallicheskih chastits. Algoritm vyichisleniy [Spectrophotometric method for determining the dynamic polarizability of ultradisperse metallic particles. The calculation algorithm],” Opt. Spectrosc. , vol. 70, no. 1, pp. 161–163, 1991.
O. V. Machulianskyi, M. K. Rodionov, and O. V. Borisov, “Otsenka funktsii raspredeleniya po razmeram ultradispersnyih chastits kondensatov nikelya i hroma [Assessment of function of distribution by the sizes of ultradisperse particles of condensates of nickel and chrome],” Electron. Commun. , vol. 7, no. 15, pp. 133–136, 2002.
A. Machulyansky, B. Babych, and V. Machulyansky, “Modelling of electromagnetic parameters of two-dimensional nanostructural system taking into account statistics of distribution of nanoparticles on the sizes,” in IX International scientific conference “Functional base of nanoelectronics,” 2017.
V. A. Zlenko and S. I. Protsenko, “Nanorazmernyie ostrovkovyie strukturyi na poliimidnoy podlozhke [Nano-sized island structures on a polyimide substrate],” in 20-ya Mezhdunarodnaya Kryimskaya konferentsiya “SVCh-tehnika i telekommunikatsionnyie tehnologii,” 2010.
V. T. Gmurman, Teoriya veroyatnostey i matematicheskaya statistika [Theory of probability and mathematical statistics] . Moscow, Russia: Vyisshaya shkola, 2001.
M. Gadenne and J. Lafait, “Optical properties of Ni from 0.03 to 6 eV,” J. Phys. , vol. 47, no. 8, pp. 1405–1410, 1986, DOI: 10.1051/jphys:019860047080140500 .
P. Johnson and R. Christy, “Optical constants of transition metals: Ti, V, Cr, Mn, Fe, Co, Ni, and Pd,” Phys. Rev. B , vol. 9, no. 12, pp. 5056–5070, 1974, DOI: 10.1103/PhysRevB.9.5056 .
E. A. Bondar’, “The anomalous optical absorption of discontinuous silver films and the polarizability of small particles,” Thin Solid Films , vol. 81, no. 2, pp. 121–130, 1981, DOI: 10.1016/0040-6090(81)90298-4 .
A. V. Rakov, Spektrofotometriya tonkoplenochnyih poluprovodnikovyih struktur [Spectrophotometry of thin-film semiconductor structures] . Moscow, USSR: Sov. radio, 1976.
L. Genzel, T. P. Martin, and U. Kreibig, “Dielectric function and plasma resonances of small metal particles,” Zeitschrift f � r Phys. B Condens. Matter Quanta , vol. 21, no. 4, pp. 339–346, 1975, DOI: 10.1007/BF01325393 .
A. Borisova, B. Babych, A. Machulyansky, V. Verbitsky, and Y. Yakimenko, “Dimensional dependencies of optical parameters of nanodimensional metal particles,” in 2016 IEEE 36th International Conference on Electronics and Nanotechnology (ELNANO) , 2016, pp. 140–143, DOI: 10.1109/ELNANO.2016.7493032 .

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§ 06 — Related

[1] Y. I. Petrov, Fizika malyih chastits [Physics of small particles] . Moscow, USSR: Nauka, 1982.

[2] A. Borisova, B. Babych, V. Verbitskiy, A. Machulyansky, M. Rodionov, and Y. Yakimenko, “Energy-efficient optically transparent coating based on a metal-dielectric composites,” in 2015 IEEE 35th International Conference on Electronics and Nanotechnology (ELNANO) , 2015, pp. 93–96, DOI: 10.1109/ELNANO.2015.7146842 .

[3] E. Moulin, J. Sukmanowski, P. Luo, R. Carius, F. X. Royer, and H. Stiebig, “Improved light absorption in thin-film silicon solar cells by integration of silver nanoparticles,” J. Non. Cryst. Solids , vol. 354, no. 19–25, pp. 2488–2491, 2008, DOI: 10.1016/j.jnoncrysol.2007.09.031 .

[4] A. Borisova et al. , “Modeling of metal-dielectric nanocomposite coatings with ferromagnetic inclusions for electromagnetic protection of electronic devices,” in 2014 IEEE 34th International Scientific Conference on Electronics and Nanotechnology (ELNANO) , 2014, pp. 139–141, DOI: 10.1109/ELNANO.2014.6873955 .

[5] I. S. Edel’man et al. , “Microstructure and magnetooptics of silicon oxide with implanted nickel nanoparticles,” J. Exp. Theor. Phys. , vol. 113, no. 6, pp. 1040–1049, 2011, DOI: 10.1134/S1063776111160035 .

[6] A. V. Kalenskii, M. V. Anan’eva, A. A. Zvekov, and I. Y. Zykov, “Spektralnaya zavisimost kriticheskoy plotnosti energii initsiirovaniya kompozitov na osnove pentaeritrittetranitrata s nanochastitsami nikelya [Spectrum dependence of the critical energy density of composites based on pentaerythritol tetranitrate with nikel nanoparticles],” Basic Probl. Mater. Sci. , vol. 11, no. 3, pp. 340–345, 2014, URL: http://www.nsmds.ru/journal/720.html .

[7] A. Borisova, B. B. A. Machulyansky, M. Rodionov, and Y. Yakimenko, “Properties of aluminum oxynitride films prepared by reactive magnetron sputtering,” in 2014 IEEE 34th International Scientific Conference on Electronics and Nanotechnology (ELNANO) , 2014, pp. 188–190, DOI: 10.1109/ELNANO.2014.6873942 .

[8] E. A. Bondar, “Razmernyie zavisimosti opticheskih harakteristik malyih chastits serebra v vyisokochastotnoy oblasti spektra [Size dependences of the optical characteristics of small silver particles in the high-frequency region of the spectrum],” Opt. Spectrosc. , vol. 77, no. 3, pp. 414–420, 1994.

[9] O. V. Machulianskyi, “Razmernyie zavisimosti dinamicheskoy polyarizuemosti ultradispersnyih chastits [Dimensional dependences of the dynamic polarizability of ultradisperse particles],” Electron. Commun. , vol. 6, no. 10, pp. 78–80, 2001.

[10] J. P. Marton and M. Schlesinger, “Optical Constants of Thin Discontinuous Nickel Films,” J. Appl. Phys. , vol. 40, no. 11, pp. 4529–4533, 1969, DOI: 10.1063/1.1657227 .

[11] G. V. Rozenbepg, Optika tonkosloynyih pokryitiy [Optics of thin-layer coatings] . Moscow, USSR, 1958.

[12] E. A. Bondar and A. V. Machulianskyi, “Spektrofotometricheskiy metod opredeleniya dinamicheskoy polyarizuemosti ultradispersnyih metallicheskih chastits. Algoritm vyichisleniy [Spectrophotometric method for determining the dynamic polarizability of ultradisperse metallic particles. The calculation algorithm],” Opt. Spectrosc. , vol. 70, no. 1, pp. 161–163, 1991.

[13] O. V. Machulianskyi, M. K. Rodionov, and O. V. Borisov, “Otsenka funktsii raspredeleniya po razmeram ultradispersnyih chastits kondensatov nikelya i hroma [Assessment of function of distribution by the sizes of ultradisperse particles of condensates of nickel and chrome],” Electron. Commun. , vol. 7, no. 15, pp. 133–136, 2002.

[14] A. Machulyansky, B. Babych, and V. Machulyansky, “Modelling of electromagnetic parameters of two-dimensional nanostructural system taking into account statistics of distribution of nanoparticles on the sizes,” in IX International scientific conference “Functional base of nanoelectronics,” 2017.

[15] V. A. Zlenko and S. I. Protsenko, “Nanorazmernyie ostrovkovyie strukturyi na poliimidnoy podlozhke [Nano-sized island structures on a polyimide substrate],” in 20-ya Mezhdunarodnaya Kryimskaya konferentsiya “SVCh-tehnika i telekommunikatsionnyie tehnologii,” 2010.

[16] V. T. Gmurman, Teoriya veroyatnostey i matematicheskaya statistika [Theory of probability and mathematical statistics] . Moscow, Russia: Vyisshaya shkola, 2001.

[17] M. Gadenne and J. Lafait, “Optical properties of Ni from 0.03 to 6 eV,” J. Phys. , vol. 47, no. 8, pp. 1405–1410, 1986, DOI: 10.1051/jphys:019860047080140500 .

[18] P. Johnson and R. Christy, “Optical constants of transition metals: Ti, V, Cr, Mn, Fe, Co, Ni, and Pd,” Phys. Rev. B , vol. 9, no. 12, pp. 5056–5070, 1974, DOI: 10.1103/PhysRevB.9.5056 .

[19] E. A. Bondar’, “The anomalous optical absorption of discontinuous silver films and the polarizability of small particles,” Thin Solid Films , vol. 81, no. 2, pp. 121–130, 1981, DOI: 10.1016/0040-6090(81)90298-4 .

[20] A. V. Rakov, Spektrofotometriya tonkoplenochnyih poluprovodnikovyih struktur [Spectrophotometry of thin-film semiconductor structures] . Moscow, USSR: Sov. radio, 1976.

[21] L. Genzel, T. P. Martin, and U. Kreibig, “Dielectric function and plasma resonances of small metal particles,” Zeitschrift f � r Phys. B Condens. Matter Quanta , vol. 21, no. 4, pp. 339–346, 1975, DOI: 10.1007/BF01325393 .

[22] A. Borisova, B. Babych, A. Machulyansky, V. Verbitsky, and Y. Yakimenko, “Dimensional dependencies of optical parameters of nanodimensional metal particles,” in 2016 IEEE 36th International Conference on Electronics and Nanotechnology (ELNANO) , 2016, pp. 140–143, DOI: 10.1109/ELNANO.2016.7493032 .

Optical properties of nickel nanoparticles in systems with a statistically inhomogeneous structure

Abstract

Keywords

References

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