КОРОЗІЙНА СТІЙКІСТЬ ГАЛЬВАНІЧНИХ НІКЕЛЕВИХ ОСАДІВ Й ЕЛЕКТРОХІМІЧНА АКТИВНІСТЬ ПРОДУКТІВ ЇХ КОРОЗІЇ

Дмитро Ущаповський; Ольга Лінючева; Георгій Васильєв; Олександр Лінючев; Андрій Кушмирук; Раїса Редько; Гліб Підвашецький; Тарас Куроченко

doi:10.20535/kpisn.2022.1-2.253045

Vol. 135 · Issue 1-2 · 2022 Jun 1, 2020 article

CORROSION RESISTANCE OF GALVANIC NICKEL DEPOSITS AND ELECTROCHEMICAL ACTIVITY OF THEIR CORROSION PRODUCTS

Dmytro Uschapovskyi Corresponding Національний технічний університет України "Київський політехнічний інститут", Кафедра технології електрохімічних виробництв, Ukraine Ukraine

Olga Linyucheva Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського», Ukraine Ukraine

Georgyi Vasiliev Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського» , Ukraine Ukraine

Oleksander Liniuchev Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського» , Ukraine Ukraine

Andrey Kushmyruk Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського», Ukraine Ukraine

Raisa Redko Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського», Ukraine Ukraine

Gleb Pidvashetsky Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського» , Ukraine Ukraine

Taras Kurochenko Національний технічний університет України «Київський політехнічний інститут імені Ігоря Сікорського, Ukraine Ukraine

PublishedJun 1, 2020

PDF (Ukrainian)

KPISN 1-2 VOL 135 · 1-2

VOL 135 · ISS 1-2 · 2022 View issue

Abstract

Background. Bright galvanic nickel coatings, with high sulphur content, are less corrosion resistant than matte. Bright nickel coatings are particularly susceptible to corrosion damage in conditions that simulate tropical humid climates and are characterized by the presence of acetic acid vapours. Objective. The purpose of the paper is to investigate: corrosion resistance of galvanic nickel deposits in concentrated acetic acid and its vapours, electrochemical activity of sulphide-containing corrosion products of bright nickel coatings. Methods. Potentiodynamic and cyclic volt-amperometry have been used to study the electrochemical activity of galvanic nickel deposits and their corrosion products. The corrosion rate of galvanic nickel deposits has been determined by gravimetric method. Investigation of surface morphology and composition of galvanic deposits were performed using scanning electron microscopy and X-ray fluorescence analysis. Results. The increased electrochemical activity of sulphide corrosion products of bright nickel coatings is evidenced by an order of magnitude higher cathodic current densities of CVA curves obtained in acetate buffer solutions, in comparison with bright and matte nickel galvanic deposits. It has been shown that at the deposition of sulphide corrosion products of bright nickel coatings on matte nickel foil the corrosion rate of last one increase at the exposition in concentrated acetic acid and its vapours. Conclusions. Significant intensifying effect of sulphur on the corrosion of galvanic nickel deposits in concentrated acetic acid and its vapours has been established. In particular, this can be explained by the decomposition of nickel sulphide (which incorporates in the coating) in acetic acid. Sulphur in the oxidation state (-2) interacts with passive oxide coatings to form an adsorbed monolayer, which leads to the transition of nickel to the active state. Further research will focus on a deeper study of the electrochemical properties of corrosion products of bright nickel coatings.

Keywords

#nickel coatings #corrosion products #nickel sulphides #corrosion activity #catalyst

References

D.Y. Ushchapovskiy, S.V. Frolenkova, M.V. Byk, O.V. Linyucheva, T.I. Motronyuk, and V.V. Klus, “Effect of saccharin on corrosion resistance of bright Ni coatings under conditions simulating a wet tropical climate”,Materials Today: Proc.,vol. 6, pp. 171–177, 2019.doi: 10.1016/j.matpr.2018.10.091.
D. Yu. Ushchapovskiy, M. V. Byk, O. V. Linyucheva, S. V. Frolenkova, R. M. Red’ko, and V. V. Yakubenko, “Corrosion Resistance of Bright Nickel Coatings in the Vapor of Acetic Acid”, Mater. Sci., vol.55, pp. 656–663, 2020. doi: 10.1007/s11003-020-00356-7.
Ph. Marcus,Corrosion Mechanisms in Theory and Practice, 3thed.,Boca Raton:“CRC Press”, 2012,pp. 395–416. doi: 10.1201/b11020.
Ph. Marcus, A. Teissier, and J. Oudar,“The influence of sulphur on the dissolution and the passivation of a nickel-iron alloy. I. Electrochemical and radiotracer measurements”,Corrosion Science, vol. 24, pp. 259–268, 1984.
B. Yan, D. Krishnamurthy, Ch. H. Hendon, S. Deshpande, Y. Surendranath, and V. Viswanathan, “Surface Restructuring of Nickel Sulﬁde Generates Optimally Coordinated Active Sites for Oxygen Reduction Catalysis”,Joule, vol. 1, no. 3, pp.600–612, 2017. doi: 10.1016/j.joule.2017.08.020.
J. M. Falkowski, N. M. Concannon, B. Yan, and Y. Surendranath, “Heazlewoodite, Ni3S2: A Potent Catalyst for Oxygen Reduction to Water under Benign Conditions”,J. Am. Chem. Soc., vol.137, no. 25, pp. 7978–7981, 2015. doi: 10.1021/jacs.5b03426.
Y.F. Yuan, X.H. Xia, J.B. Wu, J.L. Yang, Y.B. Chen, and S.Y. Guo, “Nickel foam-supported porous Ni(OH)2/NiOOH composite ﬁlm as advanced pseudocapacitor material”,Electrochimica Acta, vol.56, no. 6, pp. 2627–2632, 2011. doi:10.1016/j.electacta.2010.12.001.
T. Kurochenko, D. Ushchapovskyi, A. Kushmiruk, O. Linyucheva, andR. Redko, The investigation of corrosion activity of galvanic nickel deposits and their corrosion products,in International Young Scientists Conference on Materials Science and Surface Engineering MSSE2021: Proceedings “Materials Science and Surface Engineering (MSSE2021)”, рр. 201–204.
A. I. Kushmyruk, O. V. Kosohin, O. V. Linyucheva, V. A. Reveko, and Yu. S. Miroshnychenko,“Electrochemical Behavior of Porous Titanium Electrodes in Phosphoric Acid”,Mater. Sci., vol. 51,no. 3, pp. 429–435, 2015. doi: 10.1007/s11003-015-9859-z.
G.E. Badea, and T. Badea,“Electrochemical behavior of nickel in aqueous acetic acid solutions”,Revue Roumaine de Chimie, vol.53, no. 4, pp. 291–295, 2008.
I. Tabakovic, S. Riemer, K. Tabakovic, M. Sun, and M. Kief, “Mechanism of Saccharin Transformation to Metal Sulﬁdes and Effect of Inclusions on Corrosion Susceptibility of Electroplated CoFe Magnetic Films”, J. Electrochem. Soc., vol. 153, no. 8, pp. 586–593, 2006. doi: 10.1149/1.2207821.
J.J. Carroll, andA.E. Mather,“The solubility of hydrogen sulphide in water from 0 to 90°C and pressures to 1 MPa”,Geochimica et Cosmochimica Acta,vol. 53, no. 6, pp. 1163–1170, 1989. doi:10.1016/0016-7037(89)90053-7.

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§ 06 — Related

[1] D.Y. Ushchapovskiy, S.V. Frolenkova, M.V. Byk, O.V. Linyucheva, T.I. Motronyuk, and V.V. Klus, “Effect of saccharin on corrosion resistance of bright Ni coatings under conditions simulating a wet tropical climate”,Materials Today: Proc.,vol. 6, pp. 171–177, 2019.doi: 10.1016/j.matpr.2018.10.091.

[2] D. Yu. Ushchapovskiy, M. V. Byk, O. V. Linyucheva, S. V. Frolenkova, R. M. Red’ko, and V. V. Yakubenko, “Corrosion Resistance of Bright Nickel Coatings in the Vapor of Acetic Acid”, Mater. Sci., vol.55, pp. 656–663, 2020. doi: 10.1007/s11003-020-00356-7.

[3] Ph. Marcus,Corrosion Mechanisms in Theory and Practice, 3thed.,Boca Raton:“CRC Press”, 2012,pp. 395–416. doi: 10.1201/b11020.

[4] Ph. Marcus, A. Teissier, and J. Oudar,“The influence of sulphur on the dissolution and the passivation of a nickel-iron alloy. I. Electrochemical and radiotracer measurements”,Corrosion Science, vol. 24, pp. 259–268, 1984.

[5] B. Yan, D. Krishnamurthy, Ch. H. Hendon, S. Deshpande, Y. Surendranath, and V. Viswanathan, “Surface Restructuring of Nickel Sulﬁde Generates Optimally Coordinated Active Sites for Oxygen Reduction Catalysis”,Joule, vol. 1, no. 3, pp.600–612, 2017. doi: 10.1016/j.joule.2017.08.020.

[6] J. M. Falkowski, N. M. Concannon, B. Yan, and Y. Surendranath, “Heazlewoodite, Ni3S2: A Potent Catalyst for Oxygen Reduction to Water under Benign Conditions”,J. Am. Chem. Soc., vol.137, no. 25, pp. 7978–7981, 2015. doi: 10.1021/jacs.5b03426.

[7] Y.F. Yuan, X.H. Xia, J.B. Wu, J.L. Yang, Y.B. Chen, and S.Y. Guo, “Nickel foam-supported porous Ni(OH)2/NiOOH composite ﬁlm as advanced pseudocapacitor material”,Electrochimica Acta, vol.56, no. 6, pp. 2627–2632, 2011. doi:10.1016/j.electacta.2010.12.001.

[8] T. Kurochenko, D. Ushchapovskyi, A. Kushmiruk, O. Linyucheva, andR. Redko, The investigation of corrosion activity of galvanic nickel deposits and their corrosion products,in International Young Scientists Conference on Materials Science and Surface Engineering MSSE2021: Proceedings “Materials Science and Surface Engineering (MSSE2021)”, рр. 201–204.

[9] A. I. Kushmyruk, O. V. Kosohin, O. V. Linyucheva, V. A. Reveko, and Yu. S. Miroshnychenko,“Electrochemical Behavior of Porous Titanium Electrodes in Phosphoric Acid”,Mater. Sci., vol. 51,no. 3, pp. 429–435, 2015. doi: 10.1007/s11003-015-9859-z.

[10] G.E. Badea, and T. Badea,“Electrochemical behavior of nickel in aqueous acetic acid solutions”,Revue Roumaine de Chimie, vol.53, no. 4, pp. 291–295, 2008.

[11] I. Tabakovic, S. Riemer, K. Tabakovic, M. Sun, and M. Kief, “Mechanism of Saccharin Transformation to Metal Sulﬁdes and Effect of Inclusions on Corrosion Susceptibility of Electroplated CoFe Magnetic Films”, J. Electrochem. Soc., vol. 153, no. 8, pp. 586–593, 2006. doi: 10.1149/1.2207821.

[12] J.J. Carroll, andA.E. Mather,“The solubility of hydrogen sulphide in water from 0 to 90°C and pressures to 1 MPa”,Geochimica et Cosmochimica Acta,vol. 53, no. 6, pp. 1163–1170, 1989. doi:10.1016/0016-7037(89)90053-7.

CORROSION RESISTANCE OF GALVANIC NICKEL DEPOSITS AND ELECTROCHEMICAL ACTIVITY OF THEIR CORROSION PRODUCTS

Abstract

Keywords

References

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