ОДНОСТАДІЙНЕ ТА ПРОСТЕ ДЕКОРУВАННЯ ПЕ ПЛІВОК ГАЛУАЗИТНИМИ НАНОТРУБКАМИ

Ірина Ковінчук

doi:10.20535/kpisn.2023.1-4.297046

Vol. 136 · Issue 1-4 · 2023 Jun 1, 2020 article

SINGLE-STAGE AND SIMPLE FABRICATION OF PE FILMS DECORATED WITH HALLOYSITE NANOTUBES

Iryna Kovinchuk Corresponding National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Ukraine Ukraine

PublishedJun 1, 2020

PDF (Ukrainian)

KPISN 1-4 VOL 136 · 1-4

VOL 136 · ISS 1-4 · 2023 View issue

Abstract

Background. Environmental pollution with plastic waste is a global problem that requires the search for effective and safe ways of disposal or processing of secondary raw materials. The use of catalysts for this purpose is a promising direction for research. Objective. In this work, a method of introduction of nanomaterials on the surface of a polyethylene film by partially dissolving the upper layer of the polymer in a heated nanomaterial suspension, namely aluminosilicate halloysite nanotubes in cyclohexane, was developed. Methods. Thermogravimetric, optical, and dynamic mechanical analyses of synthesised samples were carried out, and their properties were compared with reference samples of pure polyethylene and treated without the addition of nanomaterial. Results. It was achieved by the introduction of halloysite nanotubes in the amount of a maximum of 2.83 % by mass after immersion of the film in the suspension at a temperature of 50 °C for 120 seconds. The resulting film showed a wetting angle value of 77.11o, while for the reference sample without HNT it was 99.24o, which indicates the presence of hydrophilic nanotubes in the PE surface layer. Conclusions. At the same time, the synthesised samples showed a significant decrease in mechanical properties, such as elasticity and tensile strength, due to the destructive effect of the solvent on the polymer.

Keywords

#polyethylene #halloysite #thermogravimetry #contact angle

References

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I. Kovinchuk, N. Haiuk, G. Lazzara, G. Cavallaro, and G. Sokolsky, “Enhanced photocatalytic degradation of PE film by anatase/γ-MnO2,” Polym. Degrad. Stab., vol. 210, p. 110295, Apr. 2023, doi: 10.1016/j.polymdegradstab.2023.110295.
E. Cockayne and L. Li, “First-principles DFT+U studies of the atomic, electronic, and magnetic structure of α-MnO2 (cryptomelane),” Chem. Phys. Lett., vol. 544, pp. 53–58, Aug. 2012, doi: 10.1016/j.cplett.2012.06.061.
K. Song, “Micro- and nano-fillers used in the rubber industry,” in Progress in Rubber Nanocomposites, Elsevier, 2017, pp. 41–80. doi: 10.1016/B978-0-08-100409-8.00002-4.
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T. S. Gaaz, A. B. Sulong, A. A. H. Kadhum, A. A. Al-Amiery, M. H. Nassir, and A. H. Jaaz, “The Impact of Halloysite on the Thermo-Mechanical Properties of Polymer Composites,” Molecules, vol. 22, no. 5, Art. no. 5, May 2017, doi: 10.3390/molecules22050838.
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G. Cavallaro, G. Lazzara, S. Milioto, and F. Parisi, “Halloysite nanotubes with fluorinated cavity: an innovative consolidant for paper treatment,” Clay Miner., vol. 51, no. 3, pp. 445–455, Jun. 2016, doi: 10.1180/claymin.2016.051.3.01.
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J.-H. Arndt, R. Brüll, T. Macko, F. Perez, and J. Panitzky, “Solubility of Polyethylene in n -Hexane and Cyclohexane: Experimental Determination and Comparison with Solid–Liquid Equilibria-Based Predictions,” Ind. Eng. Chem. Res., vol. 60, no. 41, pp. 14968–14976, Oct. 2021, doi: 10.1021/acs.iecr.1c02406.
M. M. Calvino, L. Lisuzzo, G. Cavallaro, G. Lazzara, and S. Milioto, “Halloysite based geopolymers filled with wax microparticles as sustainable building materials with enhanced thermo-mechanical performances,” J. Environ. Chem. Eng., vol. 10, no. 6, p. 108594, Dec. 2022, doi: 10.1016/j.jece.2022.108594.
Yu. A. Dzenis, “Effect of aggregation of a dispersed rigid filler on the elastic characteristics of a polymer composite,” Mech. Compos. Mater., vol. 22, no. 1, pp. 12–19, 1986, doi: 10.1007/BF00606002.
J. W. Sikora, I. Gajdoš, and A. Puszka, “Polyethylene-Matrix Composites with Halloysite Nanotubes with Enhanced Physical/Thermal Properties,” Polymers, vol. 11, no. 5, p. 787, May 2019, doi: 10.3390/polym11050787.

Next in issue Analysis of the influence of local electrodeposition conditions on the accuracy of electrochemical 3D-printing

§ 06 — Related

[1] C. Schmidt, T. Krauth, and S. Wagner, “Export of Plastic Debris by Rivers into the Sea,” Environ. Sci. Technol., vol. 51, no. 21, pp. 12246–12253, Nov. 2017, doi: 10.1021/acs.est.7b02368.

[2] R. T. Thomas, V. Nair, and N. Sandhyarani, “TiO2 nanoparticle assisted solid phase photocatalytic degradation of polythene film: A mechanistic investigation,” Colloids Surf. Physicochem. Eng. Asp., vol. 422, pp. 1–9, Apr. 2013, doi: 10.1016/j.colsurfa.2013.01.017.

[3] I. Kovinchuk, N. Haiuk, G. Lazzara, G. Cavallaro, and G. Sokolsky, “Enhanced photocatalytic degradation of PE film by anatase/γ-MnO2,” Polym. Degrad. Stab., vol. 210, p. 110295, Apr. 2023, doi: 10.1016/j.polymdegradstab.2023.110295.

[4] E. Cockayne and L. Li, “First-principles DFT+U studies of the atomic, electronic, and magnetic structure of α-MnO2 (cryptomelane),” Chem. Phys. Lett., vol. 544, pp. 53–58, Aug. 2012, doi: 10.1016/j.cplett.2012.06.061.

[5] K. Song, “Micro- and nano-fillers used in the rubber industry,” in Progress in Rubber Nanocomposites, Elsevier, 2017, pp. 41–80. doi: 10.1016/B978-0-08-100409-8.00002-4.

[6] E. Abdullayev and Y. Lvov, “Halloysite clay nanotubes as a ceramic ‘skeleton’ for functional biopolymer composites with sustained drug release,” J. Mater. Chem. B, vol. 1, no. 23, p. 2894, 2013, doi: 10.1039/c3tb20059k.

[7] T. S. Gaaz, A. B. Sulong, A. A. H. Kadhum, A. A. Al-Amiery, M. H. Nassir, and A. H. Jaaz, “The Impact of Halloysite on the Thermo-Mechanical Properties of Polymer Composites,” Molecules, vol. 22, no. 5, Art. no. 5, May 2017, doi: 10.3390/molecules22050838.

[8] S. Riela, M. Massaro, C. Colletti, G. Lazzara, S. Milioto, and R. Noto, “Halloysite Nanotubes as Support for Metal-Based Catalysts,” J Mater Chem A, vol. 5, May 2017, doi: 10.1039/C7TA02996A.

[9] X. u Zhao, Z. Li, Y. Chen, L. Shi, and Y. Zhu, “Solid-phase photocatalytic degradation of polyethylene plastic under UV and solar light irradiation,” J. Mol. Catal. Chem., vol. 268, no. 1–2, pp. 101–106, May 2007, doi: 10.1016/j.molcata.2006.12.012.

[10] G. Cavallaro, G. Lazzara, S. Milioto, and F. Parisi, “Halloysite nanotubes with fluorinated cavity: an innovative consolidant for paper treatment,” Clay Miner., vol. 51, no. 3, pp. 445–455, Jun. 2016, doi: 10.1180/claymin.2016.051.3.01.

[11] V. Bertolino, G. Cavallaro, S. Milioto, and G. Lazzara, “Polysaccharides/Halloysite nanotubes for smart bionanocomposite materials,” Carbohydr. Polym., vol. 245, p. 116502, Oct. 2020, doi: 10.1016/j.carbpol.2020.116502.

[12] J.-H. Arndt, R. Brüll, T. Macko, F. Perez, and J. Panitzky, “Solubility of Polyethylene in n -Hexane and Cyclohexane: Experimental Determination and Comparison with Solid–Liquid Equilibria-Based Predictions,” Ind. Eng. Chem. Res., vol. 60, no. 41, pp. 14968–14976, Oct. 2021, doi: 10.1021/acs.iecr.1c02406.

[13] M. M. Calvino, L. Lisuzzo, G. Cavallaro, G. Lazzara, and S. Milioto, “Halloysite based geopolymers filled with wax microparticles as sustainable building materials with enhanced thermo-mechanical performances,” J. Environ. Chem. Eng., vol. 10, no. 6, p. 108594, Dec. 2022, doi: 10.1016/j.jece.2022.108594.

[14] Yu. A. Dzenis, “Effect of aggregation of a dispersed rigid filler on the elastic characteristics of a polymer composite,” Mech. Compos. Mater., vol. 22, no. 1, pp. 12–19, 1986, doi: 10.1007/BF00606002.

[15] J. W. Sikora, I. Gajdoš, and A. Puszka, “Polyethylene-Matrix Composites with Halloysite Nanotubes with Enhanced Physical/Thermal Properties,” Polymers, vol. 11, no. 5, p. 787, May 2019, doi: 10.3390/polym11050787.

SINGLE-STAGE AND SIMPLE FABRICATION OF PE FILMS DECORATED WITH HALLOYSITE NANOTUBES

Abstract

Keywords

References

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